Home Page    MAP 11-47 MSDS

MAP 11-47 MSDS

SHANDONG JIAKE INTERNATIONAL TRADE CO.,LTD

Add: RM 1314,E SHANGZHU , NO. 169,YANTAI ROAD,RIZHAO,CHINA

Tel/FAX: 0086 633 8323077 email: jiate_agricultural@yeah.net


MSDSOF MAP 11-47

Material Safety Data Sheet

Revision Issued: 2/28/22Supercedes: 02/28/2022

Section I-Product and Company Identification

Product Name: MAP (Monoammonium Phosphate)

ERG No.: N/A

Common Name: Monoammonium Phosphate

Formula: (NH4) H2PO4

Synonym: MAP

Uses: Agricultural

Section II-Composition / Information On Ingredients ChemicalName :Monoammonium Phosphate

Chemical Composition : as total P2O547% by Weight

Total Nitrogen, as N 11% by Weight

Fluorides, as F0.6% by Weight

Moisture ,as 3.0% by Weight

CAS No. 7722-76-1

* For particulates not otherwise regulated, standard is 15 mg/m3 total dust and 5 mg/m3 for respirable

fraction.

**For particulates (insoluble) not otherwise specified, adopted value is 10mg/m3 for inhalable fraction

and 3 mg/m3 for respirable

fraction.

*** Product contains monoammonium phosphate as essential ingredient with small amounts

diammonium phosphate, ammonium

sulfate, urea, and aluminum/calcium/iron/magnesium phosphate compounds.

Section III-Hazard Identification

Potential Acute Health Effects:

Eyes and Skin: Contact may cause eye irritation and prolonged contact with skin may cause some irritation.

Inhalation:

High dust concentrations of air-borne material may causeirritation of the nose and upper respiratory

tract with symptoms such as sore throat and coughing. Inhalation of decomposition gases can

cause irritation and corrosive effects on the respiratory system. Some lung effects may be delayed.

Ingestion: Ingestion of small quantities are unlikely to cause toxic effect. Large quantities may give rise

to gastro-intestinal disorders.

Potential Chronic Health

Effects: No adverse effects are known.

CARCINOGENICITY LISTS IARC Monograph: No NTP: No OSHA: No

Section IV-First Aid Measures

Eyes: Immediately flush eyes (holding eyelids apart) with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.

Skin: Wash skin thoroughly with soap and water.

Ingestion: Do not induce vomiting. Drink large amounts of water (or milk if available) to dilute stomach contents. Small quantities are unlikely to cause toxic effect. Get medical attention if a large amount of MAP is ingested (small children, more than 50g).

Inhalation: Remove from source of exposure to dusts. Obtain medical attention if the effects occur. Persons who have inhaled decomposition gases (e.g. in a fire) should obtain immediate medical attention.

Section V-Fire Fighting Measures

Flash Point: Non-flammable Autoignition Temperature: Not Applicable

Lower Explosive Limit: Not Applicable Upper Explosive Limit: Not Applicable

Unusual Fire and Explosion

Hazards:

MAP is a non-flammable inorganic salt and is not flammable however when strongly heated, MAP will decompose giving off ammonia.

Extinguishing Media: Chemical type foam, CO2 (Carbon Dioxide), dry chemical, water fog.

Special Firefighting

Procedures and Equipment:

Keep personnel removed from and upwind of fire. Wear full fire-fighting turn-out gear (fullBunker gear) and respiratory protection (SCBA).

Section VI-Accidental Release Measures

Small Spill:

Spillage should be swept up and placed in chemical waste container to be disposed at an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal. Adequate ventilation is required.

Large Spill:

Contain spill and transfer the material to appropriate containers for reclamation or disposal. Dispose of material at an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal. Adequate ventilation is required.

Release Notes:

If spill could potentially enter any waterway, including intermittent dry creeks, contact the local authorities. If in the U.S., contact the US COAST GUARD NATIONAL RESPONSE CENTER toll free number 800-424-8802. In case of accident or road spill notify: CHEMTREC IN USA at 800-424-9300; CANUTEC in Canada at 613-996-6666 CHEMTREC inother countries at (International code)+1-703-527-3887. Comments:

See Section XIII for disposal information and Section XV for regulatory requirements. Large and small spills may have a broad definition depending on the user's handling system. Thereforethe spill category must be defined at the point of release by technically qualified personnel.

Section VII-Handling and Storage

Ventilation: Use with adequate ventilation.

Handling: Use appropriate personal protective equipment as specified in SectionVIII. Avoid excessive generation of dust and avoid unnecessary exposure to the atmosphere to prevent moisture pick-up. Storage: Store in dry, well ventilated area, away from potential sources of heat and fire.

Section VIII-Exposure Controls/ Personal Protection

Engineering Controls: Avoid high dust concentration and provide ventilation where necessary. Personal Protection:

Eye Protection: Wear tight fitting goggles in dusty areas to reduce dust exposure to the eyes. Protective Clothing: Wear suitablegloves when handling this product over long periods. If skin irritation occurs, wear long sleeves.

Respiratory Protection:

Wear NIOSH approved respiratory protective equipment when exposure exceeds the OSHA nuisance dust standard of 15 mg/m3 or the ACGIHnuisance dust limit of 10 mg/m3 for the eight hour time weighted

average. When stored in closed area, a self-contained breathing apparatus is required to protect against ammonia gas.

Other Protective Clothing or Equipment: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.

Section IX-Physical and Chemical Properties

Appearance/Color/Odor: Odorless granular solid with color ranging

from gray to green Boiling Point: Decomposes

Melting Point/Range: 190°C Boiling Point Range: Not Applicable

Solubility in Water: 328 g/L @ 20oC Vapor Pressure (mmHg): <1mm Hg @ 20oC

Specific Gravity: 1.8 @ 25oC Molecular Weight: 115

Vapor Density: Not Available % Volatiles: Not Available

Bulk Density: 60-64 lbs/ft3 (Loose)

65-72 lbs/ft3 (Tamped) Evaporation Rate: Not Available

pH: 4.2 in 0.2 M solution Freezing Point: Not Available

Viscosity: Not Applicable Density: Not Available

Section X-Stability and Reactivity

Stability: This product is stable undernormal conditions of storage, handling and use. Hazardous Polymerization: Will not occur

Conditions to Avoid: Welding or hot work on equipment or plant which may have contained fertilizer should not be done

without first washing thoroughly to remove allfertilizer.

Materials to Avoid

(Incompatibles): Alkalis, strong acids, copper and its alloys.

Hazardous Decomposition

Products: Ammonia is released upon reaction with strong bases or from thermal decomposition.

Section XI-Toxicological Information

Significant Routes

Exposure: Eyes, Skin, Respiratory System, Digestive Tract

Acute Oral Toxicity: (Rat) OECD Guideline 425: LD50 > 2,000 mg/kg bw Acute Inhalation Toxicity: No data available

Acute Toxicity: Other Routes: No data available

Acute Dermal Toxicity: (Rat) OECD Guideline 402: LD50 > 5,000 mg/kg bw. Repeated Dose Toxicity: No data available

Toxicity to Animals:

Eye & Skin Irritation/Corrosion: Mild Irritant

Low to very low toxicity based on the standard Federal Insecticide Fungicide andRodenticide Act (FIFRA)

ratings for mammals.

Developmental Toxicity/Teratogenicity: No data available Bacterial Genetic Toxicity In-Vitro: Gene Mutation: No data available

Non-Bacterial Genetic Toxicity In-Vitro: Chromosomal Aberration: No data available

Toxicity to Reproduction: No data available

Special Remarks on

Toxicity to Animals:

Carcinogenicity: No data available

Other Effects on Humans: Phosphate compounds such as MAP are Generally Recognized As Safe

(GRAS) by FDA for use as a

food additive for both human food and ruminant feed according to prescribed conditions.

Special Remarks on

Chronic Effects on Humans No data available

Special Remarks on Other

Effects on Humans: No data available

Section XII-Ecological Information EPA Ecological Toxicityrating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and

Rodenticide Act (FIFRA) acute toxicity ratings. Acute Toxicity to Fish: (Oncorhynchus mykiss) 96-hr: LC50 = > 85.9 mg/L Chronic Toxicity to Fish: No data available

Acute Toxicity to Aquatic

Invertebrates: No data available

Toxicity to Aquatic Plants: No data available

Toxicity to Bacteria: No data available

Toxicity to Soil Dwelling

Organisms: No data available

Ecotoxicity

Toxicity to Terrestrial Plants: No data available

Stability in Water: Stable

Stability in Soil: Stable

Environmental Fate:

Transport and Distribution:

Calculated, fugacity level III: 3.98 x 10-12 to air, 45.3% to water, 54.6% to soil, 0.0755% to sediment. Phosphates, whether water or citrate soluble, are translocated in the soil only over very short periods and are then immobilized.

Toxicity: Inorganic phosphates have the potential to increase the growth of freshwater algae, whose eventual death will reduce the available oxygen for aquatic life.

Biodegradation:

The Phosphorus cycle is well understood. Phosphates are converted to calcium or iron/aluminum phosphates or are incorporated with

Degradation Products: organic soil matter.

Photodegradation: No data available

Section XIII-Disposal Considerations

Product Disposal:

Dispose of waste at an appropriate waste disposal facility according to applicable laws and regulations. Collect in appropriate containers. Dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations and product characteristics at time of disposal. General Comments: None

Section XIV-Transportation Information

USDOT TDG - Canada

Proper Shipping Name: Not regulated Notregulated

Hazard Class:

Identification Number:

Packing Group (Technical Name):

Labeling / Placarding:

Authorized Packaging:

Notes:

European Transportation:

Section XV-Regulatory Information

This product has been reviewed according to the EPA Hazard Categories promulgated under Section 311 and 312 of the Superfund Amendment and reauthorization Act of 1986 (SARA title III) and is considered,under applicable definitions, to meet the following categories:

Fire: No Pressure

Generating: No Reactivity: No Acute: Yes Chronic: No

40 CFR Part 355 - Extremely Hazardous Substances: None

40 CFR Part 370 - Hazardous Chemical Reporting: Applicable

UNITED STATES:

SARA Hazard Category:

All intentional ingredients listed on the TSCA inventory.

SARA Title III Information: This product contains the following substances subject to the reporting requirements of Title III (EPCRA) of the Superfund amendments and Reauthorization Act of 1986 and 40 CFR Part 372:

SARA (1986) Reporting

Chemical : Monoammonium Phosphate, as P2O5 52 Percent by Weight

CAS NO. 7722-76-1

CERCLA

SARA (1986) Reporting: 311 312 313

Yes Yes No

CERCLA/Superfund, 40CFR Parts 117, 302:

If this product contains components subject to substances designated as CERCLA reportable Quantity (RQ)Substances, it will be designated in the above table with the RQ value in pounds. If there is a release of RQ Substance to the environment, notification to the National response Center, Washington D.C. (1-800-424-8802) is required.

WHMIS Hazard Symbol andClassification: This product is not WHMIS controlled.

CANADA: Ingredient Disclosure List: This product does not contain ingredient(s) on this list.

Environmental Protection: All intentional ingredients are listed on the DSL (Domestic Substance List). EINECS#: (Monoammonium Phosphate) 231-764-5

California: Prop 65: This is not a chemical known to cause cancer, nor is it listed.

Section XVI-Other Information

NFPA Hazard Ratings: Health: 1 Fire: 0 Reactivity: 0 Special Hazards:

0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme

COMMENTS:

Section(s) changed

since last revision: I, XII, XV

Although the information contained is offered in good faith, SUCH INFORMATION IS EXPRESSLY GIVEN WITHOUT ANY WARRANTY (EXPRESS OR IMPLIED) OR ANY GUARANTEE OF ITS

ACCURACY OR SUFFICIENCY and is taken at the user's sole risk. User is solely responsible for determining the suitability of use in each particular situation. PCS Sales specifically DISCLAIMS ANY LIABILITY WHATSOEVER FOR THE USE OF SUCH INFORMATION, including without limitation any recommendation which user may construe and attempt to apply which may infringe or violate valid patents, licenses, and/or copyright.