MAP 11-47 MSDS
SHANDONG JIAKE INTERNATIONAL TRADE CO.,LTD
Add: RM 1314,E SHANGZHU , NO. 169,YANTAI ROAD,RIZHAO,CHINA
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MSDSOF MAP 11-47
Material Safety Data Sheet
Revision Issued: 2/28/22Supercedes: 02/28/2022
Section I-Product and Company Identification
Product Name: MAP (Monoammonium Phosphate)
ERG No.: N/A
Common Name: Monoammonium Phosphate
Formula: (NH4) H2PO4
Synonym: MAP
Uses: Agricultural
Section II-Composition / Information On Ingredients ChemicalName :Monoammonium Phosphate
Chemical Composition : as total P2O547% by Weight
Total Nitrogen, as N 11% by Weight
Fluorides, as F0.6% by Weight
Moisture ,as 3.0% by Weight
CAS No. 7722-76-1
* For particulates not otherwise regulated, standard is 15 mg/m3 total dust and 5 mg/m3 for respirable
fraction.
**For particulates (insoluble) not otherwise specified, adopted value is 10mg/m3 for inhalable fraction
and 3 mg/m3 for respirable
fraction.
*** Product contains monoammonium phosphate as essential ingredient with small amounts
diammonium phosphate, ammonium
sulfate, urea, and aluminum/calcium/iron/magnesium phosphate compounds.
Section III-Hazard Identification
Potential Acute Health Effects:
Eyes and Skin: Contact may cause eye irritation and prolonged contact with skin may cause some irritation.
Inhalation:
High dust concentrations of air-borne material may causeirritation of the nose and upper respiratory
tract with symptoms such as sore throat and coughing. Inhalation of decomposition gases can
cause irritation and corrosive effects on the respiratory system. Some lung effects may be delayed.
Ingestion: Ingestion of small quantities are unlikely to cause toxic effect. Large quantities may give rise
to gastro-intestinal disorders.
Potential Chronic Health
Effects: No adverse effects are known.
CARCINOGENICITY LISTS IARC Monograph: No NTP: No OSHA: No
Section IV-First Aid Measures
Eyes: Immediately flush eyes (holding eyelids apart) with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Skin: Wash skin thoroughly with soap and water.
Ingestion: Do not induce vomiting. Drink large amounts of water (or milk if available) to dilute stomach contents. Small quantities are unlikely to cause toxic effect. Get medical attention if a large amount of MAP is ingested (small children, more than 50g).
Inhalation: Remove from source of exposure to dusts. Obtain medical attention if the effects occur. Persons who have inhaled decomposition gases (e.g. in a fire) should obtain immediate medical attention.
Section V-Fire Fighting Measures
Flash Point: Non-flammable Autoignition Temperature: Not Applicable
Lower Explosive Limit: Not Applicable Upper Explosive Limit: Not Applicable
Unusual Fire and Explosion
Hazards:
MAP is a non-flammable inorganic salt and is not flammable however when strongly heated, MAP will decompose giving off ammonia.
Extinguishing Media: Chemical type foam, CO2 (Carbon Dioxide), dry chemical, water fog.
Special Firefighting
Procedures and Equipment:
Keep personnel removed from and upwind of fire. Wear full fire-fighting turn-out gear (fullBunker gear) and respiratory protection (SCBA).
Section VI-Accidental Release Measures
Small Spill:
Spillage should be swept up and placed in chemical waste container to be disposed at an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal. Adequate ventilation is required.
Large Spill:
Contain spill and transfer the material to appropriate containers for reclamation or disposal. Dispose of material at an appropriate waste disposal facility according to current applicable laws and regulations and product characteristics at time of disposal. Adequate ventilation is required.
Release Notes:
If spill could potentially enter any waterway, including intermittent dry creeks, contact the local authorities. If in the U.S., contact the US COAST GUARD NATIONAL RESPONSE CENTER toll free number 800-424-8802. In case of accident or road spill notify: CHEMTREC IN USA at 800-424-9300; CANUTEC in Canada at 613-996-6666 CHEMTREC inother countries at (International code)+1-703-527-3887. Comments:
See Section XIII for disposal information and Section XV for regulatory requirements. Large and small spills may have a broad definition depending on the user's handling system. Thereforethe spill category must be defined at the point of release by technically qualified personnel.
Section VII-Handling and Storage
Ventilation: Use with adequate ventilation.
Handling: Use appropriate personal protective equipment as specified in SectionVIII. Avoid excessive generation of dust and avoid unnecessary exposure to the atmosphere to prevent moisture pick-up. Storage: Store in dry, well ventilated area, away from potential sources of heat and fire.
Section VIII-Exposure Controls/ Personal Protection
Engineering Controls: Avoid high dust concentration and provide ventilation where necessary. Personal Protection:
Eye Protection: Wear tight fitting goggles in dusty areas to reduce dust exposure to the eyes. Protective Clothing: Wear suitablegloves when handling this product over long periods. If skin irritation occurs, wear long sleeves.
Respiratory Protection:
Wear NIOSH approved respiratory protective equipment when exposure exceeds the OSHA nuisance dust standard of 15 mg/m3 or the ACGIHnuisance dust limit of 10 mg/m3 for the eight hour time weighted
average. When stored in closed area, a self-contained breathing apparatus is required to protect against ammonia gas.
Other Protective Clothing or Equipment: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Section IX-Physical and Chemical Properties
Appearance/Color/Odor: Odorless granular solid with color ranging
from gray to green Boiling Point: Decomposes
Melting Point/Range: 190°C Boiling Point Range: Not Applicable
Solubility in Water: 328 g/L @ 20oC Vapor Pressure (mmHg): <1mm Hg @ 20oC
Specific Gravity: 1.8 @ 25oC Molecular Weight: 115
Vapor Density: Not Available % Volatiles: Not Available
Bulk Density: 60-64 lbs/ft3 (Loose)
65-72 lbs/ft3 (Tamped) Evaporation Rate: Not Available
pH: 4.2 in 0.2 M solution Freezing Point: Not Available
Viscosity: Not Applicable Density: Not Available
Section X-Stability and Reactivity
Stability: This product is stable undernormal conditions of storage, handling and use. Hazardous Polymerization: Will not occur
Conditions to Avoid: Welding or hot work on equipment or plant which may have contained fertilizer should not be done
without first washing thoroughly to remove allfertilizer.
Materials to Avoid
(Incompatibles): Alkalis, strong acids, copper and its alloys.
Hazardous Decomposition
Products: Ammonia is released upon reaction with strong bases or from thermal decomposition.
Section XI-Toxicological Information
Significant Routes
Exposure: Eyes, Skin, Respiratory System, Digestive Tract
Acute Oral Toxicity: (Rat) OECD Guideline 425: LD50 > 2,000 mg/kg bw Acute Inhalation Toxicity: No data available
Acute Toxicity: Other Routes: No data available
Acute Dermal Toxicity: (Rat) OECD Guideline 402: LD50 > 5,000 mg/kg bw. Repeated Dose Toxicity: No data available
Toxicity to Animals:
Eye & Skin Irritation/Corrosion: Mild Irritant
Low to very low toxicity based on the standard Federal Insecticide Fungicide andRodenticide Act (FIFRA)
ratings for mammals.
Developmental Toxicity/Teratogenicity: No data available Bacterial Genetic Toxicity In-Vitro: Gene Mutation: No data available
Non-Bacterial Genetic Toxicity In-Vitro: Chromosomal Aberration: No data available
Toxicity to Reproduction: No data available
Special Remarks on
Toxicity to Animals:
Carcinogenicity: No data available
Other Effects on Humans: Phosphate compounds such as MAP are Generally Recognized As Safe
(GRAS) by FDA for use as a
food additive for both human food and ruminant feed according to prescribed conditions.
Special Remarks on
Chronic Effects on Humans No data available
Special Remarks on Other
Effects on Humans: No data available
Section XII-Ecological Information EPA Ecological Toxicityrating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and
Rodenticide Act (FIFRA) acute toxicity ratings. Acute Toxicity to Fish: (Oncorhynchus mykiss) 96-hr: LC50 = > 85.9 mg/L Chronic Toxicity to Fish: No data available
Acute Toxicity to Aquatic
Invertebrates: No data available
Toxicity to Aquatic Plants: No data available
Toxicity to Bacteria: No data available
Toxicity to Soil Dwelling
Organisms: No data available
Ecotoxicity
Toxicity to Terrestrial Plants: No data available
Stability in Water: Stable
Stability in Soil: Stable
Environmental Fate:
Transport and Distribution:
Calculated, fugacity level III: 3.98 x 10-12 to air, 45.3% to water, 54.6% to soil, 0.0755% to sediment. Phosphates, whether water or citrate soluble, are translocated in the soil only over very short periods and are then immobilized.
Toxicity: Inorganic phosphates have the potential to increase the growth of freshwater algae, whose eventual death will reduce the available oxygen for aquatic life.
Biodegradation:
The Phosphorus cycle is well understood. Phosphates are converted to calcium or iron/aluminum phosphates or are incorporated with
Degradation Products: organic soil matter.
Photodegradation: No data available
Section XIII-Disposal Considerations
Product Disposal:
Dispose of waste at an appropriate waste disposal facility according to applicable laws and regulations. Collect in appropriate containers. Dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations and product characteristics at time of disposal. General Comments: None
Section XIV-Transportation Information
USDOT TDG - Canada
Proper Shipping Name: Not regulated Notregulated
Hazard Class:
Identification Number:
Packing Group (Technical Name):
Labeling / Placarding:
Authorized Packaging:
Notes:
European Transportation:
Section XV-Regulatory Information
This product has been reviewed according to the EPA Hazard Categories promulgated under Section 311 and 312 of the Superfund Amendment and reauthorization Act of 1986 (SARA title III) and is considered,under applicable definitions, to meet the following categories:
Fire: No Pressure
Generating: No Reactivity: No Acute: Yes Chronic: No
40 CFR Part 355 - Extremely Hazardous Substances: None
40 CFR Part 370 - Hazardous Chemical Reporting: Applicable
UNITED STATES:
SARA Hazard Category:
All intentional ingredients listed on the TSCA inventory.
SARA Title III Information: This product contains the following substances subject to the reporting requirements of Title III (EPCRA) of the Superfund amendments and Reauthorization Act of 1986 and 40 CFR Part 372:
SARA (1986) Reporting
Chemical : Monoammonium Phosphate, as P2O5 52 Percent by Weight
CAS NO. 7722-76-1
CERCLA
SARA (1986) Reporting: 311 312 313
Yes Yes No
CERCLA/Superfund, 40CFR Parts 117, 302:
If this product contains components subject to substances designated as CERCLA reportable Quantity (RQ)Substances, it will be designated in the above table with the RQ value in pounds. If there is a release of RQ Substance to the environment, notification to the National response Center, Washington D.C. (1-800-424-8802) is required.
WHMIS Hazard Symbol andClassification: This product is not WHMIS controlled.
CANADA: Ingredient Disclosure List: This product does not contain ingredient(s) on this list.
Environmental Protection: All intentional ingredients are listed on the DSL (Domestic Substance List). EINECS#: (Monoammonium Phosphate) 231-764-5
California: Prop 65: This is not a chemical known to cause cancer, nor is it listed.
Section XVI-Other Information
NFPA Hazard Ratings: Health: 1 Fire: 0 Reactivity: 0 Special Hazards:
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
COMMENTS:
Section(s) changed
since last revision: I, XII, XV
Although the information contained is offered in good faith, SUCH INFORMATION IS EXPRESSLY GIVEN WITHOUT ANY WARRANTY (EXPRESS OR IMPLIED) OR ANY GUARANTEE OF ITS
ACCURACY OR SUFFICIENCY and is taken at the user's sole risk. User is solely responsible for determining the suitability of use in each particular situation. PCS Sales specifically DISCLAIMS ANY LIABILITY WHATSOEVER FOR THE USE OF SUCH INFORMATION, including without limitation any recommendation which user may construe and attempt to apply which may infringe or violate valid patents, licenses, and/or copyright.
